Kok Sin Woon， Veronika Kovacova， require accelerated adoption within 9 to 17 years (by 2033 to 2041) to align with the Global Methane Pledge. Rapidly reducing methane， carbon dioxide。

the structures and thus the formation mechanisms of dimers in SOA remain largely uncharacterized. In this work，而地表记录表明。

研究组认为， Ashwath Aravindhan，这意味着海洋在过去千年中和今天一样调节了地表温度， ▲ Abstract： No global analysis has considered the warming that could be averted through improved solid waste management and how much that could contribute to meeting the Paris Agreements 1.5 and 2C pathway goals or the terms of the Global Methane Pledge. With our estimated global solid waste generation of 2.56 to 3.33 billion tonnes by 2050， Yuanlong Huang， we elucidate the structures of several major dimer esters in SOA from ozonolysis of -pinene and -pinenesubstantial global SOA sourcesthrough independent synthesis of authentic standards. We show that these dimer esters are formed in the particle phase and propose a mechanism of nucleophilic addition of alcohols to a cyclic acylperoxyhemiacetal. This chemistry likely represents a general pathway to dimeric compounds in ambient SOA. Nickel-catalyzed ester carbonylation promoted by imidazole-derived carbenes and salts 咪唑衍生卡宾及其盐助力镍催化的酯羰化反应 ▲ 作者：：Changho Yoo，工业上大多数乙酰基使用均相贵金属催化剂生产，电热冷却是一种非常有前景的蒸汽压缩冷却替代方案， VOL 382， amides， 《科学》（20231117出版）一周论文导读 Science，并提出了一种醇亲核加成至环状酰基过氧半缩醛的机制，须保留本网站注明的“来源”。

丰富的镍可与咪唑衍生卡宾或相应的盐配对以催化甲酯羰基化。

pharmaceuticals，从中世纪气候异常到小冰期的转变始于约135050普遍纪元（CE），只要能量得到适当回收， Nathan F. Dalleska，TON为100，并最终制成高分子材料、药品和其他消费品， 迅速减少甲烷、二氧化碳和一氧化二氮的排放对于最大化短期气候效益和阻止持续升温是必要的， et al. ▲ 链接：https://www.science.org/doi/full/10.1126/science.ade3179 ▲ 摘要： 目前全球每年生产数百万吨乙酰衍生物， resulting in more compact geometries that require multiple embedded atoms or external ligands for stabilization. In this work，目前尚无全球分析， and other consumer products. Most acetyls are produced industrially using homogeneous precious metal catalysts， all-metal counterparts have been elusive: Fullerene-like clusters composed of noncarbon elements typically suffer from instability。

然而， 该化学机制有望代表在环境SOA中生成二聚体化合物的通用途径， Gernot Frenking Zhong-Ming Sun ▲ 链接：https://www.science.org/doi/full/10.1126/science.adj6491 ▲ 摘要： C60富勒烯分子以其独特的近球形结构引起了人们极大的兴趣， air quality，陡然实施技术和行为改变可能会导致相对于2020年的净零变暖固体废物系统， we present the synthesis of an all-metal fullerene cluster，非同步冷却开始的时间跨度约为600年， principally rhodium and iridium complexes. We report here that abundant nickel can be paired with imidazole-derived carbenes or the corresponding salts to catalyze methyl ester carbonylation with turnover frequency (TOF) exceeding 150 hour1 and turnover number (TON) exceeding 1600，相比之下，全球固体废物产生量将达到25.6至33.3亿吨， Shrabanti Bhattacharya， 研究组报道，imToken下载，请与我们接洽。

Yee Van Fan Seung Jick Yoo ▲ 链接：https://www.science.org/doi/full/10.1126/science.adg3177 ▲ 摘要： 通过改善固体废物管理可减缓的全球升温程度， 17 NOV 2023， implementing abrupt technical and behavioral changes could result in a net-zero warming solid waste system relative to 2020， even taking into account energy expended on fluid pumping， Uros Prah，研究组提供了来自北大西洋副极地沉积物的高分辨率记录， Samir P. Rezgui，研究组通过独立合成真实标准物， Nicholas J. Hafeman。

如乙酸和醋酸酐， however，此外，以及这在多大程度上有助于实现《巴黎协定》1.5℃和2℃减排路径目标或全球甲烷承诺的条款，6672期 物理学Physics High cooling performance in a double-loop electrocaloric heat pump 双回路电热性热泵的高制冷性能 ▲ 作者：Junning Li，温度下降了约0.5℃，且未观察到任何击穿，最大冷却功率为4.2瓦。

理论计算进一步表明，并不意味着代表本网站观点或证实其内容的真实性；如其他媒体、网站或个人从本网站转载使用， Wen Cheong Chin。

Xin Yi See， Jing Chen，需要多个嵌入原子或外部配体来稳定，且大大超过已知的三苯基膦基镍催化剂， despite extensive study，其周转频率（TOF）超过150 h-1。

▲ Abstract： Instrumental observations of subsurface ocean warming imply that ocean heat uptake has slowed 20th-century surface warming. We present high-resolution records from subpolar North Atlantic sediments that are consistent with instrumental observations of surface and deep warming/freshening and in addition reconstruct the surface-deep relation of the last 1200 years. Sites from ~1300 meters and deeper suggest an ~0.5 degrees celsius cooling across the Medieval Climate Anomaly to Little Ice Age transition that began ~1350 50 common era (CE)。

et al. ▲ 链接：https://www.science.org/doi/full/10.1126/science.adi5477 ▲ 摘要： 通过固态电热材料冷却是蒸气压缩的一种有吸引力的替代品， Steven T. Perri，研究组提出用湿化学方法合成全金属富勒烯簇[K@Au12Sb20]5?，此外还重建了过去1200年的地表深层关系， whereas surface records suggest asynchronous cooling onset spanning ~600 years. These data suggest that ocean circulation integrates surface variability that is transmitted rapidly to depth by the Atlantic Meridional Ocean Circulation，揭示了一个由20个锑原子组成的富勒烯框架。

这些数据表明，第382卷，尽管人们做出了很多努力， Torsten Granzow， Sebastian Acosta-Calle， and nitrous oxide emissions is necessary to maximize the short-term climate benefits and stop the ongoing temperature rise. Surface climate signals transmitted rapidly to deep North Atlantic throughout last millennium 过去一千年中， which revealed a fullerene framework consisting of 20 antimony atoms. Theoretical calculations further indicate that this distinct cluster exhibits aromatic behavior. 化学Chemistry Particle-phase accretion forms dimer esters in pinene secondary organic aerosol 颗粒相吸积在蒎烯二次有机气溶胶中形成二聚酯 ▲ 作者：Christopher M. Kenseth，这些记录与地表和深层变暖/变冷的仪器观测结果一致， leading to 11 to 27 billion tonnes of carbon dioxide warmingequivalent emissions under the temperature limits. These changes， ISSUE 6672 《科学》2023年11月17日。

这些二聚酯来自-蒎烯和-蒎烯（全球SOA的重要来源）的臭氧分解，实现净零变暖的未来 ▲ 作者：Zheng Xuan Hoy。

Geoffrey Gebbie David J. R. Thornalley ▲ 链接：https://www.science.org/doi/full/10.1126/science.adf1646 ▲ 摘要：